4/12/2025, 6:28:23 PM 星期六
含缓蚀剂钻井液对铝合金钻杆材料的腐蚀影响
CSTR:
作者:
作者单位:

1.吉林大学建设工程学院;2.中国地质调查局广州海洋地质调查局

中图分类号:

P634

基金项目:

吉林省自然科学基金(学科布局项目)“铝合金钻杆在钻井液中的腐蚀行为与腐蚀机理研究”(编号:20170101159JC);吉林省科技发展计划重点科技研发项目“高可靠性铝合金钻杆智能制造关键技术”(编号:20180201054GX);国家国际科技合作专项项目“深部油气钻探用高性能钻具系统关键技术合作研究”(编号:2013DFR70490)


Effect of drilling fluids containing corrosion inhibitors on aluminum alloy drill pipe corrosion
Author:
Affiliation:

1.College of Construction Engineering, Jilin University;2.Guangzhou Marine Geological Survey, China Geological Survey

  • 摘要
  • | |
  • 访问统计
  • |
  • 参考文献 [41]
  • |
  • 相似文献
  • |
  • 引证文献
  • | |
  • 文章评论
    摘要:

    铝合金钻杆在钻井液中发生腐蚀会引发严重的孔内事故。为了延缓钻井液对铝合金钻杆的腐蚀作用,在pH值为10、温度为70 ℃的聚磺体系钻井液中,分别加入一定比例的有机缓蚀剂(十二烷基苯磺酸钠,C18H29NaO3S或SDBS)及稀土缓蚀剂〔硫酸镧,La2(SO4)3〕,通过力学性能测试,研究缓蚀剂对7075系铝合金钻杆材料腐蚀的影响。结果表明:上述2种缓蚀剂均可降低铝合金在碱性钻井液中的腐蚀,提高铝合金钻杆抗拉强度最高达6.73%;合金中Cu、Mg、Si等元素的第二相粒子是腐蚀的敏感区域,第二相粒子脱落后即形成腐蚀坑;在产生腐蚀裂纹时,腐蚀产物主要由Al、C、O等元素组成。

    Abstract:

    Corrosion of the aluminum alloy drill pipe in the drilling fluid can affect the drilling performance and even cause serious downhole incidents. In order to improve the corrosion resistance of the aluminum alloy drill pipe, the organic corrosion inhibitor (C18H29NaO3S or SDBS) or rare earth corrosion inhibitor (La2(SO4)3) was added at some ratio to the polysulfonate drilling fluid at 10 pH and 70℃, and its effect on the 7075 aluminum alloy drill pipe corrosion was investigated through the mechanical test. The results show that both corrosion inhibitors can reduce aluminum alloy corrosion in alkaline drilling fluids, and improve the tensile strength of aluminum alloy drill pipe by up to 6.73%. The second phase particles of Cu, Mg, Si and other elements in the alloy are the corrosion-sensitive areas. Corrosion pits are formed where the second phase particles have fell off. The corrosion products mainly consist of Al, C, O and other elements.

    参考文献
    [1] 潘复生,张津,张喜燕,等.轻合金材料新技术[M].北京:化学工业出版社,2008:5-6.
    PAN Fusheng, ZHANG Jin, ZHANG Xiyan, et al. New technology of light alloy materials[M]. Beijing: Chemical Industry Press, 2008: 5-6.
    [2] 鄢泰宁,薛维,卢春华.铝合金钻杆的优越性及其在地探深孔中的应用前景[J].探矿工程(岩土钻掘工程),2010,37(02):27-29.
    YAN Taining, XUE Wei, LU Chunhua. The superiority of aluminum alloy drill pipe and its application prospect in deep trenches [J]. Exploration Engineering (Rock & Soil Drilling and Tunneling),2010,37(02):27-29.
    [3] 李振亚,秦学,余远彬,陈艳英,易玲,杨林.含镓、锡的铝合金在碱性溶液中的阳极行为[J].物理化学学报,1999,15(04):381-384.
    LI Zhenya, QIN Xue, YU Yuanbin, Chen Yanying, Yi Ling, Yang Lin. Anodic behavior of aluminum alloy containing gallium and tin in alkaline solution [J]. Acta Physico-Chimica Sinica,1994,15(04):381-384.
    [4] 王振林,唐丽文,杨惠.铝的阳极氧化工艺与氧化膜性能[J].轻合金加工技术,2010,38(02):45-48+55.
    WANG Zhenlin, TANG Liwen, YANG Hui. Anodic oxidation process and oxide film properties of aluminum[J]. Light Alloy Fabrication Technology,2010,38(02):45-48+55.
    [5] BERNARD J, CHATENET M, DALARD F.Understanding aluminum behaviour in aqueous alkaline solution using coupled techniques - Part I. Rotating ring-disk study[J]. Electrochimica Acta,2006,52(1):86-93.
    [6] 梁健,张金昌,尹浩,等.钻井利器的故事之“铝合金钻杆”[J].探矿工程(岩土钻掘工程),2018,45(05):1-3.
    LIANG Jian, ZHANG Jinchang, YIN Hao, et al. The "aluminum drill pipe" of the story of drilling tools [J]. Exploration Engineering (Rock & Soil Drilling and Tunneling), 2018,45(05):1-3.
    [7] 吕拴录,骆发前,周杰, 刘远扬,苏建文,卢强.铝合金钻杆在塔里木油田推广应用前景分析[J].石油钻探技术,2009,37(03):74-77.
    LV Yilu, LUO Faqian, ZHOU Jie, Liu Yuanyang, Su Jianwen, Lu Qiang.. Analysis of the application prospect of aluminum alloy drill pipe in Tarim Oilfield [J]. Petroleum Drilling Techniques, 2009,37(03):74-77.
    [8] 梁健,彭莉,孙建华,等.地质钻探铝合金钻杆材料研制及室内试验研究[J].地质与勘探,2011,47(02):304-308.
    LIANG Jian, PENG Li, SUN Jianhua, et al. Development and laboratory test of geological drilling aluminum alloy drill pipe materials [J].Geology and Exploration, 2011, 47 (02): 304-308.
    [9] ARMSTRONG R D,BRAHAM V J. The mechanism of aluminium corrosion in alkaline solutions[J]. Corrosion Science,1996,38(9):1463-1471.
    [10] L. S. Saakiyan, A. P. Efremov, V. M. Klyarovskii ,M. N. Orfanova. Corrosion behavior of aluminum drill pipe under interoperation storage conditions[J]. Soviet Materials Science: a transl. of Fiziko-khimicheskaya mekhanika materialov / Academy of Scinences of the Ukrainian SSR, 1985, 21 (1):83-84.
    [11] 李闯.铝合金钻杆材料在钻井液中腐蚀行为与机理研究[D].吉林大学,2018.
    LI Chuang. Study on Corrosion Behavior and Mechanism of Aluminum Alloy Drill Pipe Materials in Drilling Fluid[D]. Jilin University, 2018.
    [12] 张宝宏,丛文博,杨萍. 金属电化学腐蚀与防护[M]. 北京:化学工业出版社,2005:164-178.
    ZHANG Baohong, CONG Wenbo, YANG Ping. Electrochemical Corrosion and Protection of Metals[M]. Beijing: Chemical Industry Press, 2005:164-178.
    [13] 陈振宇,缓蚀剂开发与应用[M]. 北京:北京化学工业出版社, 2012:1-9.
    CHEN Zhenyu, Development and Application of Corrosion Inhibitors [M]. Beijing: Beijing Chemical Industry Press, 2012:1-9.
    [14] 仓辉,石文艳,邵景玲, 许琦.稀土离子与表面活性剂对金属的缓蚀协同作用.[J].江苏农业科学,2012,40(08):339-341.
    CANG Hui, SHI Wenyan, SHAO Jingling, Xu Qi. Synergistic effect of rare earth ions and surfactants on corrosion inhibition of metals[J]. Jiangsu Agricultural Sciences, 2012,40(08):339-341.
    [15] Abd El Rehim, Sayed S,HASSAN H H, MOHAMMED A A. The corrosion inhibition study of sodium dodecyl benzene sulphonate to aluminium and its alloys in 1.0 M HCl solution[J]. Materials Chemistry and Physics,2003,78(2):337-348.
    [16] ARNOTT D R, HINTON B R W, RYAN N E. Cationic-Film-Forming Inhibitors for the Protection of the AA 7075 Aluminum Alloy Against Corrosion in Aqueous Chloride Solution[J]. Corrosion, 1989,45(1):12-18.
    [17] 刘伯生.铝及铝合金上铈转化膜的研究[J].材料保护,1992,25(05):16-19+3.
    LIU Bosheng. Study on bismuth conversion coating on aluminum and aluminum alloy [J].Materials Protection, 1992,25 (05): 16-19+3.
    [18] 陆峰.稀土化合物缓蚀剂对Al2024铝合金防护的研究[J].材料工程,1998(07):10-12.
    LU Feng. Research on the protection of Al2024 aluminum alloy by rare earth compound corrosion inhibitor [J]. Journal of Materials Engineering,1998(07):10-12.
    [19] 蔡记华,谷穗,乌效鸣.松科1井(主井)取心钻进钻井液技术[J].煤田地质与勘探,2008,36(6):77-80.
    CAI Jihua, GU Sui, WU Xiaoming. Technology of Drilling Fluid Drilling in Songke 1 Well (Main Well) [J]. Coal Geology & Exploration,2008,36(6):77-80.
    [20] 郑文龙,乌效鸣,朱永宜,等.松科2井特殊钻进工艺下钻井液技术[J].石油钻采工艺,2015(3):32-35.
    ZHENG Wenlong, WU Xiaoming, ZHU Yongyi, et al. Drilling fluid technology under special drilling technology of Songke 2 well[J]. Oil Drilling & Production Technology,2015(3):32-35.
    [21] 王中华.国内外钻井液技术进展及对钻井液的有关认识[J].中外能源, 2011,16(1):48-60.
    WANG Zhonghua. Development of Drilling Fluid Technology at Home and Abroad and Relevant Understanding of Drilling Fluid[J]. Sino-Global Energy, 2011,16(1):48-60.
    [22] 中华人民共和国国家标准.GB10124-1988金属材料实验室均匀腐蚀全浸试验方法[S].北京,1990.
    National Standard of People''s Republic of China.GB10124-1988 Metallic materials-Uniform corrosion-Methods of laboratory immersion testing[S]. Beijing, 1990.
    [23] 中华人民共和国国家标准.GB/T228-2002金属材料室温拉伸试验方法[S]. 北京, 2002.
    National Standard of the People''s Republic of China. GB/T228-2002 Metallic materials--Tensile testing at ambient temperature[S]. Beijing, 2002.
    相似文献
    引证文献
引用本文

王姝婧,刘宝昌,李闯,等.含缓蚀剂钻井液对铝合金钻杆材料的腐蚀影响[J].钻探工程,2020,47(2):42-48.
WANG Shujing, LIU Baochang, LI Chuang, et al. Effect of drilling fluids containing corrosion inhibitors on aluminum alloy drill pipe corrosion[J]. Drilling Engineering, 2020,47(2):42-48.

复制
分享
文章指标
  • 点击次数:1322
  • 下载次数: 882
  • HTML阅读次数: 279
  • 引用次数: 0
历史
  • 收稿日期:2019-04-07
  • 最后修改日期:2020-01-16
  • 录用日期:2020-01-17
  • 在线发布日期: 2020-03-13
文章二维码